Product ID:WKG SOL,KODAK COLOR DEVELOPER REPLENISHER, PROCESS E-6 AR
MSDS Date:07/11/2000
FSC:NIIN:Submitter:D DG
Status Code:A
MSDS Number: CKWPW

EASTMAN KODAK COMPANY

343 STATE STREET
ROCHESTER, NY 14650
US

Emergency Phone: 716-722-5151

Info Phone: 800- 242-2424

Preparer: NOT PROVIDED

Cage: 19139

EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS

ROCHESTER, NY 14650-1115 US

Telephone: 716-722-5151/(800) 242-2424

Cage: 19139

POTASSIUM HYDROXIDE

CAS: 1310-58-3

RTECS: TT2100000

OSHA PEL NOT PROVIDED

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

WATER

CAS: 7732-18-5

RTECS: ZC0110000

TRIPOTASSIUM PHOSPHATE

CAS: 25646-71-3

RTECS: PB0431000

OSHA PEL NOT PROVIDED

ACGIH TLV: NOT PROVIDED

SODIUM SULFITE

CAS: 7757-83-7

RTECS: WE2150000

OSHA PEL NOT PROVIDED

ACGIH TLV: NOT PROVIDED

LD50 LC50 Mixture:NOT PROVIDED
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EFFECTS OF EXPOSURE: GENERAL: CONTAINS
4-(N-ETHYL-N-2-METHANESULFONYLAMINOETHYL)-2-METHYLPHENYLENEDIAMINE
SESQUISULFATE MONOHYDRATE. MAY CAUSE KIDNEY DAMAGE BASED ON ANIMAL
DATA. INHALATION: EXPECTED TO BE A LOW HAZARD FOR RECOMMENDED
HANDLING. IN CONTACT WITH STRONG ACIDS OR IF HEATED, SULFITES MAY
LIBERATE SULFUR DIOXIDE GAS. SULFUR DIOXIDE GAS IS IRRITATING TO
THE RESPIRATORY TRACT. SOME ASTHM ATICS OR HYPERSENSITIVE
INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING. EYES: CAUSES BURNS.
MIST IRRITATING. SKIN: CAUSES IRRITATION. MAY CAUSE ALLERGIC SKIN
REACTION. INGESTION: MAY BE HARMFUL IF SWA LLOWED.
Explanation of Carcinogenicity:CARCINOGENICITY CLASSIFICATION
(COMPONENTS PRESENT AT 0.1% OR MORE): - INTERNATIONAL AGENCY FOR
RESEARCH ON CANCER (IARC): NONE - AMERICAN CONFERENCE OF
GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH): SOD IUM BISULFITE, A4;
NOT CLASSIFIABLE AS A HUMAN CARCINOGEN. - NATIONAL TOXICOLOGY
PROGRAM (NTP): NONE - OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
(OSHA):NONE
Effects of Overexposure:INHALATION: IN CONTACT WITH STRONG ACIDS OR IF
HEATED, SULFITES MAY LIBERATE SULFUR DIOXIDE GAS. SULFUR DIOXIDE
GAS IS IRRITATING TO THE RESPIRATORY TRACT. SOME ASTHMATICS OR
HYPERSENSITIVE INDIVIDUA LS MAY EXPERIENCE DIFFICULT BREATHING.
EYES: CAUSES BURNS. MIST IRRITATING. SKIN: CAUSES IRRITATION. MAY
CAUSE ALLERGIC SKIN REACTION.
Medical Cond Aggravated by Exposure:SOME ASTHMATICS, HYPERSENSITIVE OR
SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING,
WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS,
WEAKNESS AND DIARRHEA.

First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. TREAT
SYMPTOMATICALLY. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. EYES:
IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET
MEDICAL ATTENTI ON IMMEDIATELY. SKIN: IMMEDIATELY FLUSH WITH PLENTY
OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED
CLOTHING AND SHOES. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
INGESTION: DO NOT INDUCE V OMITING. GIVE VICTIM A GLASS OF WATER.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. CALL A
PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY.

Flash Point:NONE
Extinguishing Media:USE APPROPRIATE AGENT FOR ADJACENT FIRE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:NONE

Spill Release Procedures:ABSORB SPILL WITH VERMICULITE OR OTHER INERT
MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN
SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
Neutralizing Agent:NOT PROVIDED

Handling and Storage Precautions:KEEP CONTAINER CLOSED. KEEP AWAY FROM
INCOMPATIBLE SUBSTANCES (SEE INCOMPATIBILITY SECTION).
Other Precautions:DO NOT GET IN EYES. AVOID CONTACT WITH SKIN. AVOID
BREATHING MIST OR VAPOR. USE WITH ADEQUATE VENTILATION. WASH
THOROUGHLY AFTER HANDLING. THE ROUTINE USE OF A NONALKALINE (ACID)
TYPE OF HAND CLEANER AND REGULAR CLEANING OF WORKING SURFACES,
GLOVES, ETC. WILL HELP MINIMIZE THE POSSIBILITY OF A SKIN
REACTION.

Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE
CONCENTRATIONS BELOW RECOMMENDED EXPOSURE LIMITS, AN APPROVED
RESPIRATOR MUST BE WORN. RESPIRATOR TYPE: HALF-FACE CARTRIDGE
RESPIRATOR WITH HIGH EFFICI ENCY PARTICULATE AEROSOL (HEPA)
CARTRIDGES. IF RESPIRATORS ARE USED, A PROGRAM SHOULD BE INSTITUTED
TO ASSURE COMPLIANCE WITH OSHA STANDARD 29 CFR 1910.134.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER
HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO
CONDITIONS.
Protective Gloves:WEAR IMPERVIOUS GLOVES AND PROTECTIVE CLOTHING
APPROPRIATE FOR RISK OF EXPOSURE
Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES) AND A
FACE SHIELD.
Other Protective Equipment:EYE BATH, SAFETY SHOWER, WASHING FACILITIES
Work Hygienic Practices:NOT PROVIDED
Supplemental Safety and Health
SUPPLEMENTARY LOCAL EXHAUST VENTILATION, CLOSED SYSTEMS, OR RESPIRATORY
PROTECTION MAY BE NEEDED IN SPECIAL CIRCUMSTANCES SUCH AS POORLY
VENTILATED SPACES, EVAPORATION FROM LARGE SURFACES, SPRAYING, H
EATING, ETC.

HCC:B3
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:>100.C, 212.F
Melt/Freeze Pt:M.P/F.P Text:NOT PROVIDED
Decomp Temp:Decomp Text:NOT PROVIDED
Vapor Pres:(68F):24 MBAR(18 MM HG)
Vapor Density:0.6
Spec Gravity:1.04
pH:12.0
Viscosity:NOT PROVIDED
Evaporation Rate & Reference:NOT PROVIDED
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS ODORLESS LIQUID.
Percent Volatiles by Volume:90- 95 WT
Corrosion Rate:NOT PROVIDED

Stability Indicator/Materials to Avoid:YES
ACIDS
Stability Condition to Avoid:NOT PROVIDED
Hazardous Decomposition Products:NONE (NONCOMBUSTIBLE)

Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL IS SUBJECT TO
NATIONAL, STATE, OR LOCAL LAWS. SINCE EMPTIED CONTAINERS RETAIN
PRODUCT RESIDUE, FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER IS
EMPTIED. CONTRACT WITH A LICENSED CHEMICAL DISPOSAL AGENCY.

Toxicological Information:DATA FOR
4-(N-ETHYL-N-2-METHANESULFONYLAMINOETHYL)-2-METHYLPHENYLENEDIAMINE
SESQUISULFATE MONOHYDRATE ACUTE TOXICITY DATA: ORAL LD-50 (MALE
RAT): 400 MG/KG (TARGET ORGAN EFFECTS: KIDNEY). ORAL LD-50
(FEMALE RAT): 246 MG/KG. DERMAL LD-50: > 1000 MG/KG (HIGHEST DOSE
TESTED). SKIN IRRITATION: SLIGHT. REPEATED SKIN APPLICATION:
MODERATE IRRITATION. SKIN SENSITIZATION: MODERATE. SKIN
SENSITIZATI ON (HUMAN): POSITIVE EYE IRRITATION (UNWASHED
EYES): MODERATE EYE IRRITATION (WASHED EYES): SLIGHT

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:THE FOLLOWING PROPERTIES ARE ESTIMATED FROM THE COMPONENTS
OF THE PREPARATIONS. POTENTIAL TOXICITY: FISH LC50 MG/L: >100.
DAPHNID EC50 MG/L: >100. ALGAL IC50 MG/L: >100. ORGANICS
READILY DEGRAD ABLE (>70%): YES (14 DAYS). POTENTIAL
BIOACCUMULATION: LOG POW <1. COD (APPROXIMATE G/L): 12. BOD5
(APPROXIMATE G/L): 2. POTENTIAL TOXICITY: WASTE TREATMENT
MICROORGANISMS EC50 (MG/L): >100.

Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS
PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE:
(716) 722-2400 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD TIME),
MONDAY THROUGH FRIDAY .

SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR
PART 372: NONE
Federal Regulatory Information:NOT PROVIDED
State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER: NONE - MATERIAL(S) KNOWN TO THE STATE
OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE